Composite of LiFePO4 with titanium phosphate phases as lithium-ion battery electrode material

Gary M. Koenig, Jiwei Ma, Baris Key, Justin Fink, Ke Bin Low, Reza Shahbazian-Yassar, Ilias Belharouak

Research output: Contribution to journalArticle

8 Citations (Scopus)

Abstract

We report the synthesis of LiFePO4 (LFP) battery materials where during synthesis the iron has been substituted by up to 10 mol % with titanium. Analysis of the Ti-substituted materials revealed that at the substitution levels investigated, the Ti did not form a solid solution with the LFP, but rather minority phases containing Ti phosphates were formed and segregated at the nanoscopic scale. The minority phases were amorphous or not well-crystallized and accepted Li on first discharge in a lithium half cell, and solid state NMR spectra were consistent with one of the constituents being LiTi2(PO4)3. The Ti substituted materials had increased electrochemical capacities and discharge voltages relative to LFP prepared in an equivalent process, and the ability to accept Li on first discharge may find utility in using previously inaccessible capacity in battery cathode formulations and in balancing excess capacity from high energy cathode materials.

Original languageEnglish
Pages (from-to)21132-21138
Number of pages7
JournalJournal of Physical Chemistry C
Volume117
Issue number41
DOIs
Publication statusPublished - 17 Oct 2013
Externally publishedYes

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electrode materials
electric batteries
phosphates
Phosphates
titanium
Titanium
lithium
minorities
Electrodes
composite materials
Composite materials
cathodes
ions
Cathodes
synthesis
solid solutions
Lithium
substitutes
solid state
formulations

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Electronic, Optical and Magnetic Materials
  • Surfaces, Coatings and Films
  • Energy(all)

Cite this

Composite of LiFePO4 with titanium phosphate phases as lithium-ion battery electrode material. / Koenig, Gary M.; Ma, Jiwei; Key, Baris; Fink, Justin; Low, Ke Bin; Shahbazian-Yassar, Reza; Belharouak, Ilias.

In: Journal of Physical Chemistry C, Vol. 117, No. 41, 17.10.2013, p. 21132-21138.

Research output: Contribution to journalArticle

Koenig, Gary M. ; Ma, Jiwei ; Key, Baris ; Fink, Justin ; Low, Ke Bin ; Shahbazian-Yassar, Reza ; Belharouak, Ilias. / Composite of LiFePO4 with titanium phosphate phases as lithium-ion battery electrode material. In: Journal of Physical Chemistry C. 2013 ; Vol. 117, No. 41. pp. 21132-21138.
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