Charge-transfer complexes of 1-(2-aminoethyl) piperazine with σ- And π-acceptors

Adel Mostafa, Hassan S. Bazzi

Research output: Contribution to journalArticle

7 Citations (Scopus)

Abstract

The solid charge-transfer (CT) molecular complexes formed in the reaction of 1-(2-aminoethyl) piperazine (AEPIP) with the σ-acceptor iodine and π-acceptors 2,3-dichloro-5,6-dicyano-1,4-benzoquinone (DDQ), 7,7,8,8-tetracyanoquinodi-methane (TCNQ), 2,4,4,6-tetrabromo-2,5- cyclohexadienone (TBCHD) and 2,3,5,6-tetrachloro-1,4-benzoquinone (CHL) were studied in chloroform at 25 °C. The products were investigated through electronic and infrared spectra as well as elemental analysis. The obtained results showed that the formed solid CT-complexes have the formulas [(AEPIP) I]+ I5-, [(AEPIP)(DDQ)2], [(AEPIP)(TCNQ)2], [(AEPIP)2(TBCHD)3] and [(AEPIP)(CHL)] which are in full agreement with the known reaction stoichiometries in solution as well as the elemental analysis measurements. The formation constant KCT, molar extinction coefficient CT, free energy change ΔG0 and CT energy ECT have been calculated for the CT-complexes [(AEPIP)(DDQ)2], [(AEPIP)(TCNQ)2] and [(AEPIP)(CHL)] as well.

Original languageEnglish
Pages (from-to)153-161
Number of pages9
JournalJournal of Molecular Structure
Volume983
Issue number1-3
DOIs
Publication statusPublished - 1 Nov 2010

Fingerprint

Charge transfer
Methane
Chloranil
piperazine
Chloroform
Chemical analysis
Stoichiometry
Iodine
Free energy
Infrared radiation

Keywords

  • 1-(2-Aminoethyl) piperazine
  • CHL
  • DDQ
  • Iodine
  • TBCHD
  • TCNQ

ASJC Scopus subject areas

  • Spectroscopy
  • Analytical Chemistry
  • Inorganic Chemistry
  • Organic Chemistry

Cite this

Charge-transfer complexes of 1-(2-aminoethyl) piperazine with σ- And π-acceptors. / Mostafa, Adel; Bazzi, Hassan S.

In: Journal of Molecular Structure, Vol. 983, No. 1-3, 01.11.2010, p. 153-161.

Research output: Contribution to journalArticle

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AB - The solid charge-transfer (CT) molecular complexes formed in the reaction of 1-(2-aminoethyl) piperazine (AEPIP) with the σ-acceptor iodine and π-acceptors 2,3-dichloro-5,6-dicyano-1,4-benzoquinone (DDQ), 7,7,8,8-tetracyanoquinodi-methane (TCNQ), 2,4,4,6-tetrabromo-2,5- cyclohexadienone (TBCHD) and 2,3,5,6-tetrachloro-1,4-benzoquinone (CHL) were studied in chloroform at 25 °C. The products were investigated through electronic and infrared spectra as well as elemental analysis. The obtained results showed that the formed solid CT-complexes have the formulas [(AEPIP) I]+ I5-, [(AEPIP)(DDQ)2], [(AEPIP)(TCNQ)2], [(AEPIP)2(TBCHD)3] and [(AEPIP)(CHL)] which are in full agreement with the known reaction stoichiometries in solution as well as the elemental analysis measurements. The formation constant KCT, molar extinction coefficient CT, free energy change ΔG0 and CT energy ECT have been calculated for the CT-complexes [(AEPIP)(DDQ)2], [(AEPIP)(TCNQ)2] and [(AEPIP)(CHL)] as well.

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