Changing the oxothiomolybdate ring from an anionic to a cationic receptor

Jean François Lemonnier, Sébastien Floquet, Jérôme Marrot, Ali Kachmar, Marc Bénard, Marie Madeleine Rohmer, Mohamed Haouas, Francis Taulelle, Marc Henry, Emmanuel Cadot

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4 Citations (Scopus)

Abstract

The ionic recognition properties of neutral oxothiomolybdenum wheels can be changed from anionic to cationic through ionization of the internal aquo ligands. In the solid state, [Mo8O8S8(OH) 10(H2O)]2- (1) interacts with two Cs + cations to give a close supramolecular host-guest arrangement. Such interactions appear to be maintained in solution as a labile association.

Original languageEnglish
Pages (from-to)9516-9518
Number of pages3
JournalInorganic Chemistry
Volume46
Issue number23
DOIs
Publication statusPublished - 12 Nov 2007

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ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry

Cite this

Lemonnier, J. F., Floquet, S., Marrot, J., Kachmar, A., Bénard, M., Rohmer, M. M., Haouas, M., Taulelle, F., Henry, M., & Cadot, E. (2007). Changing the oxothiomolybdate ring from an anionic to a cationic receptor. Inorganic Chemistry, 46(23), 9516-9518. https://doi.org/10.1021/ic701432s