Changing the oxothiomolybdate ring from an anionic to a cationic receptor

Jean François Lemonnier, Sébastien Floquet, Jérôme Marrot, Ali Kachmar, Marc Bénard, Marie Madeleine Rohmer, Mohamed Haouas, Francis Taulelle, Marc Henry, Emmanuel Cadot

Research output: Contribution to journalArticle

4 Citations (Scopus)

Abstract

The ionic recognition properties of neutral oxothiomolybdenum wheels can be changed from anionic to cationic through ionization of the internal aquo ligands. In the solid state, [Mo8O8S8(OH) 10(H2O)]2- (1) interacts with two Cs + cations to give a close supramolecular host-guest arrangement. Such interactions appear to be maintained in solution as a labile association.

Original languageEnglish
Pages (from-to)9516-9518
Number of pages3
JournalInorganic Chemistry
Volume46
Issue number23
DOIs
Publication statusPublished - 12 Nov 2007
Externally publishedYes

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wheels
Ionization
Cations
Wheels
Association reactions
Ligands
solid state
cations
ionization
ligands
rings
interactions

ASJC Scopus subject areas

  • Inorganic Chemistry

Cite this

Lemonnier, J. F., Floquet, S., Marrot, J., Kachmar, A., Bénard, M., Rohmer, M. M., ... Cadot, E. (2007). Changing the oxothiomolybdate ring from an anionic to a cationic receptor. Inorganic Chemistry, 46(23), 9516-9518. https://doi.org/10.1021/ic701432s

Changing the oxothiomolybdate ring from an anionic to a cationic receptor. / Lemonnier, Jean François; Floquet, Sébastien; Marrot, Jérôme; Kachmar, Ali; Bénard, Marc; Rohmer, Marie Madeleine; Haouas, Mohamed; Taulelle, Francis; Henry, Marc; Cadot, Emmanuel.

In: Inorganic Chemistry, Vol. 46, No. 23, 12.11.2007, p. 9516-9518.

Research output: Contribution to journalArticle

Lemonnier, JF, Floquet, S, Marrot, J, Kachmar, A, Bénard, M, Rohmer, MM, Haouas, M, Taulelle, F, Henry, M & Cadot, E 2007, 'Changing the oxothiomolybdate ring from an anionic to a cationic receptor', Inorganic Chemistry, vol. 46, no. 23, pp. 9516-9518. https://doi.org/10.1021/ic701432s
Lemonnier JF, Floquet S, Marrot J, Kachmar A, Bénard M, Rohmer MM et al. Changing the oxothiomolybdate ring from an anionic to a cationic receptor. Inorganic Chemistry. 2007 Nov 12;46(23):9516-9518. https://doi.org/10.1021/ic701432s
Lemonnier, Jean François ; Floquet, Sébastien ; Marrot, Jérôme ; Kachmar, Ali ; Bénard, Marc ; Rohmer, Marie Madeleine ; Haouas, Mohamed ; Taulelle, Francis ; Henry, Marc ; Cadot, Emmanuel. / Changing the oxothiomolybdate ring from an anionic to a cationic receptor. In: Inorganic Chemistry. 2007 ; Vol. 46, No. 23. pp. 9516-9518.
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