Bimetallic palladium-supported halloysite nanotubes for low temperature CO oxidation: Experimental and DFT insights

Yahia H. Ahmad, Assem T. Mohamed, Walid M.I. Hassan, Ahmed Soliman, Khaled Mahmoud, Amina S. Aljaber, Siham Y. Al-Qaradawi

Research output: Contribution to journalArticle

1 Citation (Scopus)

Abstract

The design and fabrication of novel metal-supported catalysts for energy conversion and heterogeneous catalysis is a pivotal theme. Herein, we present the synthesis of bimetallic palladium nanoalloys supported on halloysite nanotubes, PdM@HNTs, where M = Co, Cu, and Ni and their catalytic performance towards CO oxidation. The synthesis procedure involves simple co-reduction of the metals precursors using NaBH4 on halloysite nanotubes support. The synthesized catalysts retain the tubular morphology of halloysite support with surface area of 90–107 m2 g−1. Transmission electron microscopy (TEM) revealed smaller size for bimetallic nanoparticles (6–8 nm) compared to Pd (14 nm). PdNi displayed the highest catalytic activity towards CO oxidation. Moreover, PdCo and PdNi demonstrated enhanced CO oxidation kinetics compared to PdCu and PdNi as revealed from the calculated activation energies. DFT calculations revealed that the order of catalytic activity is PdNi > PdCo > PdCu > Pd which is in agreement with the experimental results and that the adsorption energy of CO2 on the different catalysts has no apparent role in the whole activity of the catalyst. In conclusion, PdM@HNTs catalysts expressed homogeneous distribution for metallic nanoparticles as well as high dispersion and expressed promising potential to be applied in real flare control processes.

Original languageEnglish
Pages (from-to)70-80
Number of pages11
JournalApplied Surface Science
Volume493
DOIs
Publication statusPublished - 1 Nov 2019

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Design for testability
Palladium
Carbon Monoxide
Nanotubes
palladium
nanotubes
Catalyst supports
catalysts
Catalyst activity
Oxidation
oxidation
Catalysts
Metals
catalytic activity
Nanoparticles
Temperature
nanoparticles
Energy conversion
Discrete Fourier transforms
Catalysis

Keywords

  • Binary alloy
  • CO oxidation
  • DFT
  • Halloysite nanotubes
  • Palladium

ASJC Scopus subject areas

  • Chemistry(all)
  • Condensed Matter Physics
  • Physics and Astronomy(all)
  • Surfaces and Interfaces
  • Surfaces, Coatings and Films

Cite this

Bimetallic palladium-supported halloysite nanotubes for low temperature CO oxidation : Experimental and DFT insights. / Ahmad, Yahia H.; Mohamed, Assem T.; Hassan, Walid M.I.; Soliman, Ahmed; Mahmoud, Khaled; Aljaber, Amina S.; Al-Qaradawi, Siham Y.

In: Applied Surface Science, Vol. 493, 01.11.2019, p. 70-80.

Research output: Contribution to journalArticle

Ahmad, Yahia H. ; Mohamed, Assem T. ; Hassan, Walid M.I. ; Soliman, Ahmed ; Mahmoud, Khaled ; Aljaber, Amina S. ; Al-Qaradawi, Siham Y. / Bimetallic palladium-supported halloysite nanotubes for low temperature CO oxidation : Experimental and DFT insights. In: Applied Surface Science. 2019 ; Vol. 493. pp. 70-80.
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