Aberration-corrected scanning transmission electron microscopy: From atomic imaging and analysis to solving energy problems

S. J. Pennycook, M. F. Chisholm, A. R. Lupini, M. Varela, A. Y. Borisevich, M. P. Oxley, W. D. Luo, K. Van Benthem, S. H. Oh, D. L. Sales, S. I. Molina, J. GarcíA-Barriocanal, C. Leon, J. SantamaríA, Sergey Rashkeev, S. T. Pantelides

Research output: Contribution to journalArticle

60 Citations (Scopus)

Abstract

The new possibilities of aberration-corrected scanning transmission electron microscopy (STEM) extend far beyond the factor of 2 or more in lateral resolution that was the original motivation. The smaller probe also gives enhanced single atom sensitivity, both for imaging and for spectroscopy, enabling light elements to be detected in a Z-contrast image and giving much improved phase contrast imaging using the bright field detector with pixel-by-pixel correlation with the Z-contrast image. Furthermore, the increased probe-forming aperture brings significant depth sensitivity and the possibility of optical sectioning to extract information in three dimensions. This paper reviews these recent advances with reference to several applications of relevance to energy, the origin of the low-temperature catalytic activity of nanophase AU, the nucleation and growth of semiconducting nanowires, and the origin of the eight orders of magnitude increased ionic conductivity in oxide superlattices. Possible future directions ofaberration-corrected STEM for solving energy problems are outlined.

Original languageEnglish
Pages (from-to)3709-3733
Number of pages25
JournalPhilosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences
Volume367
Issue number1903
DOIs
Publication statusPublished - 28 Sep 2009
Externally publishedYes

    Fingerprint

Keywords

  • Electron energy loss spectroscopy
  • Scanning transmission electron microscopy
  • Z-contrast

ASJC Scopus subject areas

  • Mathematics(all)
  • Physics and Astronomy(all)
  • Engineering(all)

Cite this

Pennycook, S. J., Chisholm, M. F., Lupini, A. R., Varela, M., Borisevich, A. Y., Oxley, M. P., Luo, W. D., Benthem, K. V., Oh, S. H., Sales, D. L., Molina, S. I., GarcíA-Barriocanal, J., Leon, C., SantamaríA, J., Rashkeev, S., & Pantelides, S. T. (2009). Aberration-corrected scanning transmission electron microscopy: From atomic imaging and analysis to solving energy problems. Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences, 367(1903), 3709-3733. https://doi.org/10.1098/rsta.2009.0112