A unified model for stiffness modulus of amorphous polymers across transition temperatures and strain rates

J. Richeton, G. Schlatter, K. S. Vecchio, Y. Rémond, Said Ahzi

Research output: Contribution to journalArticle

95 Citations (Scopus)

Abstract

In many applications, polymer materials undergo a large variety of mechanical loading conditions, wherein the influences of temperature and strain rate are of prime importance. Mahieux and Reifsnider [Mahieux CA, Reifsnider KL. Polymer 2001;42:3281. [19]] have proposed a statistical model to describe the stiffness variation of polymers over a wide range of temperatures. However, this model does not consider any frequency/strain rate dependence of the stiffness modulus. Starting from this consideration, we propose here to transform this latter model into a robust physically based model for the prediction of the stiffness modulus for a wide range of temperatures and frequencies/strain rates. This new formulation has been successfully validated for two amorphous polymers, polymethylmethacrylate (PMMA) and polycarbonate (PC), using dynamic mechanical analysis and uniaxial compression testing. Good agreement has been found between theory and experiment for the non-linear behavior of the initial Young's modulus, at the very high strain rates.

Original languageEnglish
Pages (from-to)8194-8201
Number of pages8
JournalPolymer
Volume46
Issue number19 SPEC. ISS.
DOIs
Publication statusPublished - 8 Sep 2005
Externally publishedYes

Fingerprint

Superconducting transition temperature
Strain rate
Polymers
Stiffness
polycarbonate
Compression testing
Polymethyl Methacrylate
Dynamic mechanical analysis
Polycarbonates
Temperature
Elastic moduli
Experiments

Keywords

  • High strain rate
  • Stiffness modulus
  • Temperature

ASJC Scopus subject areas

  • Organic Chemistry
  • Polymers and Plastics

Cite this

A unified model for stiffness modulus of amorphous polymers across transition temperatures and strain rates. / Richeton, J.; Schlatter, G.; Vecchio, K. S.; Rémond, Y.; Ahzi, Said.

In: Polymer, Vol. 46, No. 19 SPEC. ISS., 08.09.2005, p. 8194-8201.

Research output: Contribution to journalArticle

Richeton, J. ; Schlatter, G. ; Vecchio, K. S. ; Rémond, Y. ; Ahzi, Said. / A unified model for stiffness modulus of amorphous polymers across transition temperatures and strain rates. In: Polymer. 2005 ; Vol. 46, No. 19 SPEC. ISS. pp. 8194-8201.
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