A new, three-component cobalt-catalysed domino reaction leading to ferrocenyl-tetrahydro-4(1H)-pyrimidinone derivatives

János Balogh, Zsolt Csók, László Párkányi, Ferenc Ungváry, László Kollár, Rita Skoda-Földes

Research output: Contribution to journalArticle

5 Citations (Scopus)

Abstract

The use of N-(alkyl/arylmethyl)-ferrocenylimines as ketene scavengers in the cobalt-catalysed carbonylation of ethyl diazoacetate resulted in the formation of tetrahydro-4(1H)-pyrimidinones as the main products. The structures of the new compounds were determined by various NMR techniques including 2D measurements. In some cases, the stereochemistry was proved by X-ray crystallography.

Original languageEnglish
Pages (from-to)131-138
Number of pages8
JournalJournal of Organometallic Chemistry
Volume718
DOIs
Publication statusPublished - 1 Nov 2012
Externally publishedYes

Fingerprint

Pyrimidinones
Carbonylation
Stereochemistry
X ray crystallography
X Ray Crystallography
stereochemistry
Cobalt
crystallography
cobalt
Nuclear magnetic resonance
Derivatives
nuclear magnetic resonance
products
x rays
ketene
diazoacetic ester

Keywords

  • Carbonylation
  • Cobalt
  • Domino reactions
  • Ferrocenes
  • Schiff bases

ASJC Scopus subject areas

  • Inorganic Chemistry
  • Organic Chemistry
  • Physical and Theoretical Chemistry
  • Materials Chemistry
  • Biochemistry

Cite this

A new, three-component cobalt-catalysed domino reaction leading to ferrocenyl-tetrahydro-4(1H)-pyrimidinone derivatives. / Balogh, János; Csók, Zsolt; Párkányi, László; Ungváry, Ferenc; Kollár, László; Skoda-Földes, Rita.

In: Journal of Organometallic Chemistry, Vol. 718, 01.11.2012, p. 131-138.

Research output: Contribution to journalArticle

Balogh, János ; Csók, Zsolt ; Párkányi, László ; Ungváry, Ferenc ; Kollár, László ; Skoda-Földes, Rita. / A new, three-component cobalt-catalysed domino reaction leading to ferrocenyl-tetrahydro-4(1H)-pyrimidinone derivatives. In: Journal of Organometallic Chemistry. 2012 ; Vol. 718. pp. 131-138.
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